Abstracts

Development of a Reference Database for Chemical Bonding Analysis

The different concepts of chemical bonding are not only relevant for molecular chemistry, but also for us materials chemists dealing with extended solids.

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Electron Density Studies on Cobalt Single-Molecule Magnets

In 2021 Stalke et al. analysed several tetrahedral distorted Co2+ complexes and predicted that a bite angle between 76-78° maximises the magnetic anisotropy, as it minimises the energy gap between the dxy and dx2-y2 orbital. The closer the orbitals are in energy, the larger is the magnetic anisotropy

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Round Table discussion

Various topics in quantum crystallography will be discussed in a round table format.

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Similarities and Differences in the Electron Density of Cumulated and Conjugated Systems

QTAIM calculations were conducted to shed light on the nature of bonds in even and odd cumulated systems, with n = 3, 4, 5 and 6, functionalized with alkyls, aryls and N-heterocyclic carbenes (NHCs).

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The agreement between DFT and CASSCF of a Cr(I)-Cr(I) study

The metal-metal interaction fascinated scientist for many years. In this study, the Cr(I)-Cr(I) bond of complex S was studied by both single- and multi-determinant approaches.

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Structural and optical properties of benzotriazole-based 2D hybrid perovskites

Over the past decade, hybrid organic-inorganic perovskites (HOIPs) have received significant research consideration mainly because of their use as active layers in perovskite solar cells

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